TIP NO. 01 - I suggest asking what some of their (the brand) objectives are. From there you can get a feeling of where they are even willing to go and grow…and if what you may want to do aligns with their goals! When you know, you’ll have a prime opening to pitch your idea, showing them how their objectives can be reached.
TIP No. 02 - You can also do the direct, but laid back approach - In order to move the relationship beyond the status quo, ask them, in a casual manner, if they may be interested in X (a paid opportunity) that would even more thoroughly spotlight the brand on your site, or casually send them your media kit, in case they might be interested in some sponsored opportunity in the coming months. Keeping it professional, but casual, should make it comfortable to approach.
TIP NO. 03 - When it comes to remaining memorable, we that you show some common courtesy: In any kind of relationship, being attentive, diligent, and making them a priority (i.e. attending the brand’s events, posting info about them as soon as it’s released) is much-appreciated…doing something courteous and considerate, that requires minimal effort, like sending a thank-you email or even hand written note after you've worked with them on something really can make a difference in distinguishing yourself from the rest.
TIP NO 04 - Believe in yourself, have a game plan, and be professional!